Uniphos - Ống đo khí ứng dụng: Container
Fumigation
Hãng sản xuất: Uniphos –Ấn Độ
Tham khảo tại: http://www.uniphos.eu/container-fumigation
-
Các
container được chuyển đến nhiều nơi trên thế giới, để loại bỏ sâu bệnh của động
vật không mong muốn, các vi khuẩn không có cơ hội tồn tại; các container sẽ bị
khử trùng với các khí cực độc, sẽ ảnh hưởng đến hệ thống thần kinh. Khi
container đến các cảng bãi, công nhân sẽ đo các khí độc này trước khi mở
-
Ngoài
các khí khử trùng, sẽ có các khí ô nhiễm khác trong container:
- Khí ô
nhiễm sinh ra do hàng hóa chuyển: các chất bốc hơi như sơn, rò rỉ bao bì,
gỗ hoặc các hàng hóa sinh vật khác
- Phản ứng
hóa học sinh ra trong quá trình vận chuyển
- Những
bao bì chứa các bình chất độc bị rò rỉ trong container
-
Các khí gặp phải: Methyl Bromide, Acetaldehyde, Ammonia, Benzene, HCN,
Butylacetate, Chloropicrine, 1,2 Dichloroethane, Dichloromethane, Formaldehyde,
Phosphine, Carbon Dioxide, Carbon Monoxide, Pinene, Styrene, Toluene,
Trichloroethylene, Vinyl Acetate, Xylene, Hydrogen Sulphide.
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Loại hàng hóa
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Khí cần đo
|
Ghi chú
|
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Apricots
|
Methyl
Bromide
|
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Artificial
Flowers
|
Phosphine
|
|
|
Formaldehyde
|
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|
Xyleen
|
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Asparagus
|
Phosphine
|
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Bags
|
Phosphine
|
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|
Formaldehyde
|
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Bags
(plastic & printed)
|
Toluene
|
|
|
Benzene
|
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Bamboo
|
Methyl
Bromide
Phosphine |
|
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Barley
|
Phosphine
|
|
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Baskets
(cane)
|
Carbon
Monoxide
|
|
|
Carbon
Dioxide
|
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|
Phosphine
|
||
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Methyl
Bromide
|
||
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Chloropicrin
|
||
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Formaldehyde
|
||
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Batteries
|
Hydrogen
(LEL)
|
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Camphene
|
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Octanal
|
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Nonanal
|
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Urea
|
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Isoborneol
|
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2
Propenoic acid
|
||
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Bedding
|
Phosphine
|
|
|
Formaldehyde
|
||
|
Bicycle
parts
|
Benzene
|
|
|
Bikes
|
Formaldehyde
|
|
|
Blankets
|
Formaldehyde
|
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Boon
(mung)
|
Phosphine
|
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Methyl
Bromide
|
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Boots
|
Benzene
|
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Bottles
|
Phosphine
|
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Boxes
(wooden)
|
α Pinene
|
|
|
Formaldehyde
|
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Cacao
|
Phosphine
|
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Cacaobutter
|
Methyl
Bromide
|
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Canned
food
|
Phosphine
|
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Carbon
Monoxide
|
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Carbonate
|
Phosphine
|
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Carpets
|
Toluene
|
Toluene
is probably not in the carpets themselves, but in the packaging material,
since the carpets are often wrapped in thick plastic.
|
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Carrot
seeds
|
Carbon
Monoxide
|
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Cars
|
Benzene
|
|
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Phosphine
|
||
|
Formaldehyde
|
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Casino
tables
|
1,2
Dichloorethane
|
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Cereals
|
Carbon
Monoxide
|
Cargo
came from Sweden.
|
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Chairs
(metal)
|
Carbon
Monoxide
|
|
|
Formaldehyde
|
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|
Chairs
(wood & metal)
|
Methyl
Bromide
|
Methyl
Bromide because of the wood, formaldehyde because of the glue. If the
chairs have a metal frame or bottom, there may also be Trichlorethylene in
there as they clean metal with this.
|
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Trichloorethyleen
|
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Formaldehyde
|
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Chloropicrin
|
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Cherries
|
Phosphine
|
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Chipboard
|
Formaldehyde
|
|
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Chive
|
Phosphine
|
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Christmas
items
|
Benzene
|
|
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1,2
Dichloroethane
|
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|
Phosphine
|
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Clothing
|
Formaldehyde
|
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Benzene
|
||
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Toluene
|
||
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1,2
Dichloroethane
|
||
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Carbon
Disulphide
|
||
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Phosphine
|
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Coconuts
(ground)
|
Carbon
Dioxide
|
|
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Carbon
Monoxide
|
||
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Coffee
|
Phosphine
|
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|
Formaldehyde
|
||
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Coffee
beans
|
Phosphine
|
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Carbon
Monoxide
|
||
|
Dates
|
Phosphine
|
|
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Methyl
Bromide
|
||
|
Chloropicrin
|
||
|
Decoration
material
|
Phosphine
|
|
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Dog
basket (fabric)
|
Carbon
Monoxide
|
|
|
Formaldehyde
|
||
|
Easter
products
|
Hexane
|
1,2
dibromoethane is extremely carcinogenic and has a very low detection
limit of 0.0003 ppm.
|
|
(iso)Pentane
|
||
|
Heptane
|
||
|
1,2
Dibromemethane
|
||
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Electric
motors
|
Phosphine
|
|
|
Electronics
|
Benzene
|
|
|
LEL
|
||
|
Firework
|
Phosphine
|
|
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Fitness
devices
|
1,2
Dichloroethane
|
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|
Methyl
Bromide
|
||
|
Fitted sheets
|
Toluene
|
|
|
Formaldehyde
|
||
|
Flour
|
Phosphine
|
|
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Flowers
|
Phosphine
|
|
|
Formic
acid
|
Carbon
Monoxide
|
|
|
Fountains
|
1,2
Dichloroethane
|
|
|
Methyl
Bromide
|
||
|
Benzene
|
||
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Fruit
(dried)
|
Methyl
Bromide
|
|
|
Chloropicrin
|
||
|
Furniture
|
Methyl
Bromide
|
|
|
Formaldehyde
|
||
|
Phosphine
|
||
|
Chloropicrin
|
||
|
Garden
statues
|
1,2
Dichloroethane
|
|
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Gears
|
Benzene
|
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Glassware
|
Phosphine
|
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|
Formaldehyde
|
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|
Gloves
|
Phosphine
|
|
|
Formaldehyde
|
||
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Glowsticks
|
Benzene
|
|
|
Hexane
|
||
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Glue
stick
|
Methyl
Bromide
|
|
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Handtrucks
|
Carbon
Monoxide
|
|
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Hats
|
Phosphine
|
|
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Honey
(in drums)
|
Formaldehyde
|
|
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Household
items
|
Methyl
Bromide
|
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Phosphine
|
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Hydrogen
Cyanide
|
||
|
Carbon
Monoxide
|
||
|
Carbon
Dioxide
|
||
|
Formaldehyde
|
||
|
Chloropicrin
|
||
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Inflatable
boats
|
Carbon
Monoxide
|
|
|
Benzene
|
||
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Inflatable
letters
|
Formaldehyde
|
|
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1,2
Dichloroethane
|
||
|
Benzene
|
||
|
Toluene
|
||
|
Ink
|
Formaldehyde
|
|
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Irons
|
Phosphine
|
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Jackets
|
Phosphine
|
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Formaldehyde
|
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Lamps
|
Formaldehyde
|
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Laptop
bags
|
Ammonia
|
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Benzene
|
||
|
Toluene
|
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Carbon
Monoxide
|
||
|
Formaldehyde
|
||
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Latex
|
Phosphine
|
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Limestone
|
Carbon
Dioxide
|
|
|
Machine
parts
|
1,2
Dichloroethane
|
|
|
Methyl
Bromide
|
||
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Mantles
|
Formaldehyde
|
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Mattresses
|
Methyl
Bromide
|
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Benzene
|
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|
Toluene
|
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1,2
Dichloroethane
|
||
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Methylene
Chloride
|
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Carbon
Disulphide
|
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Meat pin
(wood)
|
Carbon
Monoxide
|
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Medical
equipment
|
Ethylene
Oxide
|
|
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Medications
|
Methyl
Bromide
|
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Carbon
Sulphide
|
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|
Formaldehyde
|
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Mirrors
|
Formaldehyde
|
|
|
Phosphine
|
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Monitors
(computer)
|
(Iso)pentane
|
For
computer monitors it is usually (iso)-pentane where the PID, LEL and the
tubes react on. When you suspect there is (iso) pentane in the
container, you can use the following rejection rule (all 3 should be
higher as the given concentration):
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|
Toluene
|
- PID 80
or higher
|
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Styrene
|
- LEL 5
or higher
|
|
|
1,2
Dichloroethane
|
-
Reading on pentane tube 800 ppm or higher
|
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|
Hexane
|
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Xylene
|
|
|
|
LEL
|
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|
Moving
containers
|
Methyl
Bromide
|
|
|
Carbon
Monoxide
|
||
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Phosphine
|
||
|
Formaldehyde
|
||
|
Musical
instruments
|
Phosphine
|
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|
Nail
polish
|
Formaldehyde
|
|
|
Nail
polish remover
|
Formaldehyde
|
|
|
Notebooks
|
Phosphine
|
|
|
Nutrition
(general)
|
Methyl
Bromide
|
|
|
Methyleenchloride
|
||
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Carbon
Sulphide
|
||
|
Chloropicrin
|
||
|
Formaldehyde
|
||
|
Phosphine
|
||
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Nuts
|
Phosphine
|
|
|
Blauwzuur
|
||
|
Ammonia
|
||
|
Nuts
(Cashew)
|
Methyl
Bromide
|
On
October 2010 there has been 450 (!) ppm phosphine found in a vacuum packed
bag!
|
|
Chloropicrin
|
||
|
Phosphine
|
||
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Nuts
(ground)
|
Phosphine
|
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|
Office
chairs
|
Phosphine
|
|
|
Onions
|
Phosphine
|
|
|
Formaldehyde
|
||
|
Oregano
|
Methyl
Bromide
|
|
|
Chloropicrin
|
||
|
Painting
pots
|
Butylacetate
|
|
|
Vinylacetate
|
||
|
Pallets
(wood)
|
Methyl
Bromide
|
|
|
Paper
|
Formaldehyde
|
|
|
Picture
frames
|
Benzene
|
|
|
LEL
|
||
|
Pillows
|
Formaldehyde
|
|
|
Trichloroethane
|
||
|
Pillows
(decorative)
|
Carbon
Monoxide
|
|
|
Pine
nuts
|
Carbon
Monoxide
|
Values
of both carbon monoxide and dioxide can sometimes really add up.
|
|
Carbon
Dioxide
|
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|
Planters
|
Styrene
|
The
planters were packed in styrofoam. The styrene was in the styrofoam.
|
|
Plastic
(general)
|
Toluene
|
Benzene,
toluene, xylene, styrene, etc., used as a solvent. Ammonia is used
as a degreaser.
|
|
Benzene
|
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|
Xyleen
|
||
|
Styreen
|
||
|
1,2
Dichloroethane
|
||
|
Ammonia
|
||
|
Plastic
books for children
|
Toluene
|
|
|
Benzene
|
||
|
Formaldehyde
|
||
|
Plastic
bottles (Spa, Cola, etc.)
|
Benzene
|
|
|
Toluene
|
||
|
Plastic
toys
|
Formaldehyde
|
|
|
1,2
Dichloroethane
|
||
|
Benzene
|
||
|
Toluene
|
||
|
Plums
|
Phosphine
|
|
|
Poppy
seed
|
Phosphine
|
|
|
Pots
(stone)
|
Toluene
|
|
|
Pottery
|
Carbon
Monoxide
|
|
|
Pullovers
|
Phosphine
|
|
|
Formaldehyde
|
||
|
Rabbit
Hutches
|
α
Pinene
|
α-pinene
is characterized by a strong pine air.
|
|
Raisins
|
Phosphine
|
|
|
Hydrogen
Cyanide
|
||
|
Refrigerators
|
Carbon
Dioxide
|
|
|
1,1
Dichloro 1 Fluoroethane
|
||
|
Rice
|
Carbon
Dioxide
|
|
|
1,1
Dichloro 1 Fluoroethane
|
||
|
Rolls of
film
|
Dichloromethane
|
|
|
Rubber
|
Phosphine
|
|
|
Methyl
Bromide
|
||
|
Chloropicrin
|
||
|
Screws
|
Phosphine
|
|
|
Formaldehyde
|
||
|
Shampoo
|
Formaldehyde
|
|
|
Shoes
|
Toluene
|
|
|
Benzene
|
||
|
Formaldehyde
|
||
|
Ammonia
|
||
|
Carbon
Sulphide
|
||
|
1,2
Dichloroethane
|
||
|
Phosphine
|
||
|
Cyclohexane
|
||
|
Shopping
bag
|
Formaldehyde
|
|
|
Slippers
|
Methyl
Bromide
|
|
|
Toluene
|
||
|
Benzene
|
||
|
Ammonia
|
||
|
Formaldehyde
|
||
|
Sockets
|
Benzene
|
|
|
Stamps
(for children)
|
1,2
Dichloroethane
|
Op
14/11/09 the Ministry has found a load of 1,2 dichloroethane in a freight of
children stamps in such huge amount, that the police in The Netherlands
decided to make an official report for importing a toxic gas!
|
|
Stone
(natural)
|
Methyl
Bromide
|
The
stone are being shipped in wooden crates. Methyl bromide can be in
there.
|
|
Hydrogen
Sulphide
|
Hydrogen
sulphide is quite rare, but is there sometimes anyway.
|
|
|
Formaldehyde
|
|
|
|
Carbon
Dioxide
|
Through
natural processes sometimes there can be insufficient oxygen in the
container.
|
|
|
Styrofoam
|
Styrene
|
|
|
(Iso)pentane
|
||
|
Suitcases
|
Phosphine
|
|
|
Sunflower
seeds
|
Phosphine
|
In a
load of sunflower seeds in two containers from Turkey in December 2009, there
has been respectively 10 and 2.3 ppm Phosphine encountered, and on March 2010
even 15 ppm Phosphine (took two weeks to get the container gas free)!
|
|
Textile
|
Formaldehyde
|
|
|
Phosphine
|
||
|
Toluene
|
||
|
Chloropicrin
|
||
|
Ties
|
Ethanol
|
|
|
Carbon
Monoxide
|
||
|
Ammonia
|
||
|
Formaldehyde
|
||
|
Toasters
|
Ammonia
|
|
|
Tobacco
|
Methyl
Bromide
|
|
|
Phosphine
|
||
|
Formaldehyde
|
||
|
Toilet
seats
|
Phosphine
|
|
|
Toothpaste
|
Phosphine
|
|
|
Toy guns
|
1,2
Dichloroethane
|
|
|
Toys
|
Benzene
|
|
|
Methyl
Bromide
|
||
|
Toluene
|
||
|
1,2
Dichloroethane
|
||
|
1,2
chloorpropeen
|
||
|
Formaldehyde
|
||
|
Phosphine
|
||
|
Blauwzuur
|
||
|
Transformers
|
Methyl
Bromide Chloropicrin
|
|
|
Trash
(Dangerous)
|
Phosphine
|
|
|
USB
Sticks etc.
|
Benzene
|
|
|
Toluene
|
||
|
Formaldehyde
|
||
|
Vacuum
cleaners
|
Phosphine
|
|
|
Formaldehyde
|
||
|
Wallets
|
Benzene
|
|
|
Toluene
|
||
|
Carbon
Monoxide
|
||
|
Formaldehyde
|
||
|
Water
tap
|
Phosphine
|
|
|
Water
pipe
|
Phosphine
|
|
|
Formaldehyde
|
||
|
Weir
wood
|
Methyl
Bromide
|
|
|
Phosphine
|
||
|
Whetstones
|
Methyl
Bromide
|
|
|
Chloropicrin
|
||
|
Wine
|
Methyl
Bromide
|
|
|
Chloropicrin
|
||
|
Wishing
stones
|
1,2
Dichloroethane
|
|
|
Methyl
Bromide
|
||
|
Wood
(unmodified)
|
Methyl
Bromide
|
|
|
Phosphine
|
||
|
Hydrogen
Cyanide
|
||
|
Carbon
Monoxide
|
||
|
Carbon
Dioxide
|
||
|
Formaldehyde
|
||
|
Chloropicrin
|
||
|
Wool
|
Phosphine
|
|
|
Yeast
|
Methyl
Bromide
|
|
|
Chloropicrin
|
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