Chủ Nhật, 20 tháng 9, 2015

Uniphos - Ống đo khí ứng dụng: Container Fumigation Hãng sản xuất: Uniphos –Ấn Độ

Uniphos - Ống đo khí ứng dụng: Container Fumigation
Hãng sản xuất: Uniphos –Ấn Độ


-          Các container được chuyển đến nhiều nơi trên thế giới, để loại bỏ sâu bệnh của động vật không mong muốn, các vi khuẩn không có cơ hội tồn tại; các container sẽ bị khử trùng với các khí cực độc, sẽ ảnh hưởng đến hệ thống thần kinh. Khi container đến các cảng bãi, công nhân sẽ đo các khí độc này trước khi mở
-          Ngoài các khí khử trùng, sẽ có các khí ô nhiễm khác trong container:
  • Khí ô nhiễm sinh ra do hàng hóa chuyển: các chất bốc hơi như sơn, rò rỉ bao bì, gỗ hoặc các hàng hóa sinh vật khác
  • Phản ứng hóa học sinh ra trong quá trình vận chuyển
  • Những bao bì chứa các bình chất độc bị rò rỉ trong container
-          Các khí gặp phải: Methyl Bromide, Acetaldehyde, Ammonia, Benzene, HCN, Butylacetate, Chloropicrine, 1,2 Dichloroethane, Dichloromethane, Formaldehyde, Phosphine, Carbon Dioxide, Carbon Monoxide, Pinene, Styrene, Toluene, Trichloroethylene, Vinyl Acetate, Xylene, Hydrogen Sulphide.
Loại hàng hóa
Khí cần đo
Ghi chú
Apricots
Methyl Bromide

Artificial Flowers
Phosphine

Formaldehyde
Xyleen
Asparagus
Phosphine

Bags
Phosphine

Formaldehyde
Bags (plastic & printed)
Toluene

Benzene
Bamboo
Methyl Bromide                
Phosphine

Barley
Phosphine

Baskets (cane)
Carbon Monoxide

Carbon Dioxide
Phosphine
Methyl Bromide
Chloropicrin
Formaldehyde
Batteries
Hydrogen (LEL)

Camphene
Octanal
Nonanal
Urea
Isoborneol
2 Propenoic acid
Bedding
Phosphine

Formaldehyde
Bicycle parts
Benzene

Bikes
Formaldehyde

Blankets
Formaldehyde

Boon (mung)
Phosphine

Methyl Bromide
Boots
Benzene

Bottles
Phosphine

Boxes (wooden)
α Pinene

Formaldehyde
Cacao
Phosphine

Cacaobutter
Methyl Bromide

Canned food
Phosphine

Carbon Monoxide
Carbonate
Phosphine

Carpets
Toluene
Toluene is probably not in the carpets themselves, but in the packaging material, since the carpets are often wrapped in thick plastic.
Carrot seeds
Carbon Monoxide

Cars
Benzene

Phosphine
Formaldehyde
Casino tables
1,2 Dichloorethane

Cereals
Carbon Monoxide
Cargo came from Sweden.
Chairs (metal)
Carbon Monoxide

Formaldehyde
Chairs (wood & metal)
Methyl Bromide
Methyl Bromide because of the wood, formaldehyde because of the glue. If the chairs have a metal frame or bottom, there may also be Trichlorethylene in there as they clean metal with this. 
Trichloorethyleen
Formaldehyde
Chloropicrin
Cherries
Phosphine

Chipboard
Formaldehyde

Chive
Phosphine

Christmas items
Benzene

1,2 Dichloroethane
Phosphine
Clothing
Formaldehyde

Benzene
Toluene
1,2 Dichloroethane
Carbon Disulphide
Phosphine
Coconuts (ground)
Carbon Dioxide

Carbon Monoxide
Coffee
Phosphine

Formaldehyde
Coffee beans
Phosphine

Carbon Monoxide
Dates
Phosphine

Methyl Bromide
Chloropicrin
Decoration material
Phosphine

Dog basket (fabric)
Carbon Monoxide

Formaldehyde
Easter products
Hexane
1,2 dibromoethane is extremely carcinogenic and has a very low detection limit of 0.0003 ppm.
(iso)Pentane
Heptane
1,2 Dibromemethane
Electric motors
Phosphine

Electronics
Benzene

LEL
Firework
Phosphine

Fitness devices
1,2 Dichloroethane

Methyl Bromide
Fitted sheets
Toluene

Formaldehyde
Flour
Phosphine

Flowers
Phosphine

Formic acid
Carbon Monoxide

Fountains
1,2 Dichloroethane

Methyl Bromide
Benzene
Fruit (dried)
Methyl Bromide

Chloropicrin
Furniture
Methyl Bromide

Formaldehyde
Phosphine
Chloropicrin
Garden statues
1,2 Dichloroethane

Gears
Benzene

Glassware
Phosphine

Formaldehyde
Gloves
Phosphine

Formaldehyde
Glowsticks
Benzene

Hexane
Glue stick
Methyl Bromide

Handtrucks
Carbon Monoxide

Hats
Phosphine

Honey (in drums)
Formaldehyde

Household items
Methyl Bromide

Phosphine
Hydrogen Cyanide
Carbon Monoxide
Carbon Dioxide
Formaldehyde
Chloropicrin
Inflatable boats
Carbon Monoxide

Benzene
Inflatable letters
Formaldehyde

1,2 Dichloroethane
Benzene
Toluene
Ink
Formaldehyde

Irons
Phosphine

Jackets
Phosphine

Formaldehyde
Lamps
Formaldehyde

Laptop bags
Ammonia

Benzene
Toluene
Carbon Monoxide
Formaldehyde
Latex
Phosphine

Limestone
Carbon Dioxide

Machine parts
1,2 Dichloroethane

Methyl Bromide
Mantles
Formaldehyde

Mattresses
Methyl Bromide

Benzene
Toluene
1,2 Dichloroethane
Methylene Chloride
Carbon Disulphide
Meat pin (wood)
Carbon Monoxide

Medical equipment
Ethylene Oxide

Medications
Methyl Bromide

Carbon Sulphide
Formaldehyde
Mirrors
Formaldehyde

Phosphine
Monitors (computer)
(Iso)pentane
For computer monitors it is usually (iso)-pentane where the PID, LEL and the tubes react on. When you suspect there is (iso) pentane in the container, you can use the following rejection rule (all 3 should be higher as the given concentration):
Toluene
- PID 80 or higher
Styrene
- LEL 5 or higher
1,2 Dichloroethane
- Reading on pentane tube 800 ppm or higher
Hexane

Xylene

LEL

Moving containers
Methyl Bromide

Carbon Monoxide
Phosphine
Formaldehyde
Musical instruments
Phosphine

Nail polish
Formaldehyde

Nail polish remover
Formaldehyde

Notebooks
Phosphine

Nutrition (general)
Methyl Bromide

Methyleenchloride
Carbon Sulphide
Chloropicrin
Formaldehyde
Phosphine
Nuts
Phosphine

Blauwzuur
Ammonia
Nuts (Cashew)
Methyl Bromide
On October 2010 there has been 450 (!) ppm phosphine found in a vacuum packed bag!
Chloropicrin
Phosphine
Nuts (ground)
Phosphine

Office chairs
Phosphine

Onions
Phosphine

Formaldehyde
Oregano
Methyl Bromide

Chloropicrin
Painting pots
Butylacetate

Vinylacetate
Pallets (wood)
Methyl Bromide

Paper
Formaldehyde

Picture frames
Benzene

LEL
Pillows
Formaldehyde

Trichloroethane
Pillows (decorative)
Carbon Monoxide

Pine nuts
Carbon Monoxide
Values of both carbon monoxide and dioxide can sometimes really add up.
Carbon Dioxide
Planters
Styrene
The planters were packed in styrofoam. The styrene was in the styrofoam.
Plastic (general)
Toluene
Benzene, toluene, xylene, styrene, etc., used as a solvent. Ammonia is used as a degreaser. 
Benzene
Xyleen
Styreen
1,2 Dichloroethane
Ammonia
Plastic books for children
Toluene

Benzene
Formaldehyde
Plastic bottles (Spa, Cola, etc.)
Benzene

Toluene
Plastic toys
Formaldehyde

1,2 Dichloroethane
Benzene
Toluene
Plums
Phosphine

Poppy seed
Phosphine

Pots (stone)
Toluene

Pottery
Carbon Monoxide

Pullovers
Phosphine

Formaldehyde
Rabbit Hutches
α Pinene 
α-pinene is characterized by a strong pine air.
Raisins
Phosphine

Hydrogen Cyanide
Refrigerators
Carbon Dioxide

1,1 Dichloro 1 Fluoroethane
Rice
Carbon Dioxide

1,1 Dichloro 1 Fluoroethane
Rolls of film
Dichloromethane

Rubber
Phosphine

Methyl Bromide
Chloropicrin
Screws
Phosphine

Formaldehyde
Shampoo
Formaldehyde

Shoes
Toluene

Benzene
Formaldehyde
Ammonia
Carbon Sulphide
1,2 Dichloroethane
Phosphine
Cyclohexane
Shopping bag
Formaldehyde

Slippers
Methyl Bromide

Toluene
Benzene
Ammonia
Formaldehyde
Sockets
Benzene

Stamps (for children)
1,2 Dichloroethane
Op 14/11/09 the Ministry has found a load of 1,2 dichloroethane in a freight of children stamps in such huge amount,  that the police in The Netherlands decided to make an official report for importing a toxic gas!
Stone (natural)
Methyl Bromide
The stone are being shipped in wooden crates. Methyl bromide can be in there. 
Hydrogen Sulphide
Hydrogen sulphide is quite rare, but is there sometimes anyway.
Formaldehyde

Carbon Dioxide
Through natural processes sometimes there can be insufficient oxygen in the container.
Styrofoam
Styrene

(Iso)pentane
Suitcases
Phosphine

Sunflower seeds
Phosphine
In a load of sunflower seeds in two containers from Turkey in December 2009, there has been respectively 10 and 2.3 ppm Phosphine encountered, and on March 2010 even 15 ppm Phosphine (took two weeks to get the container gas free)!
Textile
Formaldehyde

Phosphine
Toluene
Chloropicrin
Ties
Ethanol

Carbon Monoxide
Ammonia
Formaldehyde
Toasters
Ammonia

Tobacco
Methyl Bromide

 Phosphine
 Formaldehyde
Toilet seats
Phosphine

Toothpaste
Phosphine

Toy guns
1,2 Dichloroethane

Toys
Benzene

Methyl Bromide
Toluene
1,2 Dichloroethane
1,2 chloorpropeen
Formaldehyde
Phosphine
Blauwzuur
Transformers
Methyl Bromide Chloropicrin

Trash (Dangerous)
Phosphine

USB Sticks etc.
Benzene

Toluene
Formaldehyde
Vacuum cleaners
Phosphine

Formaldehyde
Wallets
Benzene

Toluene
Carbon Monoxide
Formaldehyde
Water tap
Phosphine

Water pipe
Phosphine

Formaldehyde
Weir wood
Methyl Bromide

Phosphine
Whetstones
Methyl Bromide

Chloropicrin
Wine
Methyl Bromide

Chloropicrin
Wishing stones
1,2 Dichloroethane

 Methyl Bromide
Wood (unmodified)
Methyl Bromide

Phosphine
Hydrogen Cyanide
Carbon Monoxide
Carbon Dioxide
Formaldehyde
Chloropicrin
Wool
Phosphine

Yeast
Methyl Bromide

Chloropicrin


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